UPDATE:
Somehow the new update 5.221 reset something and now my phone connects to Calibre. Like Jackb's situation, it took about 2-1/2 minutes to scan at first, but then scanned faster the next time round.
@Kovid: Thank you for the support. And even if you didn't do anything, thank you spending time looking into the solution.
@Jackb: Your workaround solved another prob I was having with processing filenames before sending them to my phone, so I'm actually going to keep using that.
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